This was the first launch of the titanium fins. The BulgariaSat booster from two days ago was an older block 3 first stage with the "original" aluminum fins. They did glow quite a bit during the very hot re-entry, visible on the last few video frames before the feed cut out: https://youtu.be/Y8mLi-rRTh8?t=1405
Your wording makes it sound like there have been two launches with the new grid fins. For clarification, I believe you meant the second of this weekend's launches was the first to use the new grid fins.